石墨烯的尺寸对水泥基材料性能的影响Effects of graphene dimensions on the properties of cement-based materials
董健苗,何其,胡志梅,贾松林,马东楊
摘要(Abstract):
采用4种不同尺寸的石墨烯(PG1、PG2、PG3、PG4)制备石墨烯水泥基材料,并研究石墨烯尺寸对水泥基材料水化性能、力学性能的影响。试验结果表明:石墨烯的掺入提高了水泥的水化速度,降低了水泥浆体的流动性,其中小尺寸的石墨烯效果最为明显;小尺寸石墨烯有助于增强抗压强度,大尺寸石墨烯有利于提高抗折强度。通过X射线衍射仪(X-ray diffractometer, XRD)及扫描电子显微镜(scanning electron microscope, SEM)等设备分析可知,掺入4种石墨烯均未改变水泥水化产物的种类,但能够有效细化水化产物氢氧化钙(calcium hydroxide, CH)晶体的尺寸,提高水泥基体的密实度,石墨烯尺寸越小,对CH晶体的细化效果越明显。
关键词(KeyWords): 石墨烯;水泥基材料;水化性能;力学性能
基金项目(Foundation): 国家自然科学基金项目(51568009)资助
作者(Author): 董健苗,何其,胡志梅,贾松林,马东楊
DOI: 10.16375/j.cnki.cn45-1395/t.2025.04.006
参考文献(References):
- [1]董健苗,曹嘉威,王留阳,等.纤维增强自密实轻骨料混凝土早期抗裂性能试验[J].广西科技大学学报,2020,31(2):32-38.
- [2]张鹏,李清富,朱海堂,等.纳米Si O2和钢纤维增强混凝土的断裂韧度[J].建筑材料学报,2017,20(3):366-372.
- [3]刘金涛.基于纳米材料的活性粉末混凝土及其基本力学性能研究[D].杭州:浙江大学,2016.
- [4]施韬,李泽鑫,李闪闪.碳纳米管增强水泥基复合材料的自收缩及抗裂性能[J].复合材料学报,2019,36(6):1528-1535.
- [5] JUNG M,LEE Y S,HONG S G,et al. Carbon nanotubes(CNTs)in ultra-high performance concrete(UHPC):dispersion,mechanical properties,and electromagnetic interference(EMI)shielding effectiveness(SE)[J]. Cement and Concrete Research,2020,131:106017.
- [6] KOVTYUKHOVA N I,OLLIVIER P J,MARTIN B R,et al. Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations[J].Chemistry of Materials,1999,11(3):771-778.
- [7] LEE C,WEI X D,KYSAR J W,et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science,2008,321(5887):385-388.
- [8] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
- [9] REN W C,CHENG H M. The global growth of graphene[J].Nature Nanotechnology,2014,9:726-730.
- [10]董健苗,邹明璇,周铭,等.石墨烯及氧化石墨烯对水泥基材料水化过程及强度的影响[J].材料导报,2022,36(24):76-81.
- [11]彭晖,戈娅萍,杨振天,等.氧化石墨烯增强水泥基复合材料的力学性能及微观结构[J].复合材料学报,2018,35(8):2132-2139.
- [12] ZHAO L,GUO X L,LIU Y Y,et al. Hydration kinetics,pore structure,3D network calcium silicate hydrate,and mechanical behavior of graphene oxide reinforced cement composites[J]. Construction and Building Materials,2018,190:150-163.
- [13] INDUKURI C S R,NERELLA R. Enhanced transport properties of graphene oxide based cement composite material[J]. Journal of Building Engineering,2021,37:102174.
- [14] ANWAR A,MOHAMMED B S,WAHAB M A,et al.Enhanced properties of cementitious composite tailored with graphene oxide nanomaterial:a review[J]. Developments in the Built Environment,2020,1:100002.
- [15] REHMAN S K U,IBRAHIM Z,JAMEEL M,et al.Assessment of rheological and piezoresistive properties of graphene based cement composites[J]. International Journal of Concrete Structures and Materials,2018,12(1):64.
- [16] LI X Y,LU Z Y,CHUAH S,et al. Effects of graphene oxide aggregates on hydration degree,sorptivity,and tensile splitting strength of cement paste[J]. Composites Part A:Applied Science and Manufacturing,2017,100:1-8.
- [17] MAURYA S K,KOTHIYAL N C. Effect of graphene oxide and functionalized carbon nanotubes on mechanical and durability properties of high volume fly-ash cement nanocomposite[J]. European Journal of Environmental and Civil Engineering,2024,28(4):859-875.
- [18]董健苗,何其,周铭,等.石墨烯水泥砂浆抗碳化试验及预测模型分析[J].材料导报,2024,38(5):203-208.
- [19] DONG J M,ZHUANG J Q,LI W J,et al. Insights into the mechanism of graphene acting on water and chloride ion permeability of cement-based materials[J]. Materials,2023,16(10):3881.
- [20] LU Z Y,HOU D S,HANIF A,et al. Comparative evaluation on the dispersion and stability of graphene oxide in water and cement pore solution by incorporating silica fume[J]. Cement and Concrete Composites,2018,94:33-42.
- [21] INDUKURI C S R,NERELLA R,MADDURU S R C.Effect of graphene oxide on microstructure and strengthened properties of fly ash and silica fume based cement composites[J]. Construction and Building Materials,2019,229:116863.
- [22]国家市场监督管理总局,国家标准化管理委员会.水泥胶砂强度检验方法(ISO法):GB/T 17671—2021[S].北京:中国标准出版社,2021.
- [23]顾越.核壳纳米Si O2改性水泥基材料性能研究[D].南京:东南大学,2017.
- [24]沈裕盛,唐明亮,沈晓冬.水泥浆体中氢氧化钙晶体的生长习性[J].硅酸盐学报,2016,44(2):232-238.
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